Onion-type complexation based on carbon nanorings and a buckminsterfullerene

被引:114
作者
Kawase, T [1 ]
Tanaka, K [1 ]
Shiono, N [1 ]
Seirai, Y [1 ]
Oda, M [1 ]
机构
[1] Osaka Univ, Grad Sch Sci, Dept Chem, Toyonaka, Osaka 5600043, Japan
关键词
cycloalkynes; fullerenes; inclusion compounds; noncovalent interactions;
D O I
10.1002/anie.200353517
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
2 into 1 will go: Multi-inclusion structures, reminiscent of Russian Matrioshka dolls, have been constructed in nonpolar organic solvents from carbon nanorings and a C60 molecule (see picture). A study of these structures show there is a substantial difference between the electronic properties of planar and curved conjugated systems.
引用
收藏
页码:1722 / 1724
页数:3
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