Cyclodehydrogenation of poly(perylene) to poly(quaterrylene):: Toward poly(peri-naphthalene)

被引:37
作者
Former, C [1 ]
Becker, S [1 ]
Grimsdale, AC [1 ]
Müllen, K [1 ]
机构
[1] Max Planck Inst Polymer Res, D-55128 Mainz, Germany
关键词
D O I
10.1021/ma011724d
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Cyclodehydrogenation of soluble polyperylenes gives polymers containing predominantly quaterrylene units by spectral analysis. Evidence for larger rylene units is also seen. These polymers represent important intermediates toward a poly(peri-naphthalene) (PPN). Reactions on model compounds suggest that the insolubility of polymers with larger rylene units is predominantly due to the rigidity of the polymer backbone.
引用
收藏
页码:1576 / 1582
页数:7
相关论文
共 11 条
[1]   POLYARYLENES AND POLYARYLENEVINYLENES .2. OLIGORYLENE AS A MODEL FOR POLY(PERINAPHTHALENE) [J].
BOHNEN, A ;
KOCH, KH ;
LUTTKE, W ;
MULLEN, K .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1990, 29 (05) :525-527
[2]  
Brandrup J., 1999, Polymer handbook, VII
[3]   THEORETICAL-STUDY OF THE ELECTRONIC-PROPERTIES AND CRYSTAL-STRUCTURE OF POLY(PERINAPHTHALENE) - ON THE ORIGIN OF HIGH OBSERVED CONDUCTIVITIES [J].
BREDAS, JL ;
BAUGHMAN, RH .
JOURNAL OF CHEMICAL PHYSICS, 1985, 83 (03) :1316-1322
[4]  
HOUBENWEYL, 1993, OXIDATION
[5]   STRUCTURE AND OPTICAL-ABSORPTION OF OLIGORYLENES UPON DOPING [J].
KARABUNARLIEV, S ;
GHERGHEL, L ;
KOCH, KH ;
BAUMGARTEN, M .
CHEMICAL PHYSICS, 1994, 189 (01) :53-65
[6]   POLYARYLENES AND POLY(ARYLENEVINYLENE)S .5. SYNTHESIS OF TETRAALKYL-SUBSTITUTED OLIGO(1,4-NAPHTHYLENE)S AND CYCLIZATION TO SOLUBLE OLIGO(PERI-NAPHTHYLENE)S [J].
KOCH, KH ;
MULLEN, K .
CHEMISCHE BERICHTE, 1991, 124 (09) :2091-2100
[7]   DEHYDRO COUPLING OF AROMATIC NUCLEI BY CATALYST OXIDANT SYSTEMS - POLY(PARA-PHENYLENE) [J].
KOVACIC, P ;
JONES, MB .
CHEMICAL REVIEWS, 1987, 87 (02) :357-379
[8]   Novel perylene-containing polymers [J].
Quante, H ;
Schlichting, P ;
Rohr, U ;
Geerts, Y ;
Mullen, K .
MACROMOLECULAR CHEMISTRY AND PHYSICS, 1996, 197 (12) :4029-4044
[9]   Hybrid materials doped with covalently bound perylene dyes through the sol-gel process [J].
Schneider, M ;
Müllen, K .
CHEMISTRY OF MATERIALS, 2000, 12 (02) :352-362
[10]   Synthesis and characterization of rigid rod poly(p-phenylenes) [J].
Vanhee, S ;
Rulkens, R ;
Lehmann, U ;
Rosenauer, C ;
Schulze, M ;
Kohler, W ;
Wegner, G .
MACROMOLECULES, 1996, 29 (15) :5136-5142