Cyclodehydrogenation of poly(perylene) to poly(quaterrylene):: Toward poly(peri-naphthalene)

被引：37

作者：

Former, C ^{[1
]}

Becker, S ^{[1
]}

Grimsdale, AC ^{[1
]}

Müllen, K ^{[1
]}

机构：

[1] Max Planck Inst Polymer Res, D-55128 Mainz, Germany

来源：

MACROMOLECULES | 2002年 / 35卷 / 05期

关键词：

D O I：

10.1021/ma011724d

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Cyclodehydrogenation of soluble polyperylenes gives polymers containing predominantly quaterrylene units by spectral analysis. Evidence for larger rylene units is also seen. These polymers represent important intermediates toward a poly(peri-naphthalene) (PPN). Reactions on model compounds suggest that the insolubility of polymers with larger rylene units is predominantly due to the rigidity of the polymer backbone.

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收藏

页码：1576 / 1582

页数：7

相关论文

共 11 条

[1] POLYARYLENES AND POLYARYLENEVINYLENES .2. OLIGORYLENE AS A MODEL FOR POLY(PERINAPHTHALENE) [J].

BOHNEN, A ;

KOCH, KH ;

LUTTKE, W ;

MULLEN, K .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1990, 29 (05) :525-527

[2]

Brandrup J., 1999, Polymer handbook, VII

[3] THEORETICAL-STUDY OF THE ELECTRONIC-PROPERTIES AND CRYSTAL-STRUCTURE OF POLY(PERINAPHTHALENE) - ON THE ORIGIN OF HIGH OBSERVED CONDUCTIVITIES [J].

BREDAS, JL ;

BAUGHMAN, RH .

JOURNAL OF CHEMICAL PHYSICS, 1985, 83 (03) :1316-1322

[4]

HOUBENWEYL, 1993, OXIDATION

[5] STRUCTURE AND OPTICAL-ABSORPTION OF OLIGORYLENES UPON DOPING [J].

KARABUNARLIEV, S ;

GHERGHEL, L ;

KOCH, KH ;

BAUMGARTEN, M .

CHEMICAL PHYSICS, 1994, 189 (01) :53-65

[6] POLYARYLENES AND POLY(ARYLENEVINYLENE)S .5. SYNTHESIS OF TETRAALKYL-SUBSTITUTED OLIGO(1,4-NAPHTHYLENE)S AND CYCLIZATION TO SOLUBLE OLIGO(PERI-NAPHTHYLENE)S [J].

KOCH, KH ;

MULLEN, K .

CHEMISCHE BERICHTE, 1991, 124 (09) :2091-2100

[7] DEHYDRO COUPLING OF AROMATIC NUCLEI BY CATALYST OXIDANT SYSTEMS - POLY(PARA-PHENYLENE) [J].

KOVACIC, P ;

JONES, MB .

CHEMICAL REVIEWS, 1987, 87 (02) :357-379

[8] Novel perylene-containing polymers [J].

Quante, H ;

Schlichting, P ;

Rohr, U ;

Geerts, Y ;

Mullen, K .

MACROMOLECULAR CHEMISTRY AND PHYSICS, 1996, 197 (12) :4029-4044

[9] Hybrid materials doped with covalently bound perylene dyes through the sol-gel process [J].

Schneider, M ;

Müllen, K .

CHEMISTRY OF MATERIALS, 2000, 12 (02) :352-362

[10] Synthesis and characterization of rigid rod poly(p-phenylenes) [J].

Vanhee, S ;

Rulkens, R ;

Lehmann, U ;

Rosenauer, C ;

Schulze, M ;

Kohler, W ;

Wegner, G .

MACROMOLECULES, 1996, 29 (15) :5136-5142