ADMET: The Future Revealed

被引：165

作者：

Atallah, Pascale

Wagener, Kenneth B. ^{[1
]}

Schulz, Michael D.

机构：

[1] Univ Florida, Dept Chem, George & Josephine Butler Polymer Res Lab, Gainesville, FL 32611 USA

来源：

MACROMOLECULES | 2013年 / 46卷 / 12期

基金：

美国国家科学基金会;

关键词：

ACYCLIC DIENE METATHESIS; IMIDO ALKYLIDENE COMPLEXES; METAL-CONTAINING POLYMERS; OLEFIN METATHESIS; MOLECULAR-WEIGHT; RENEWABLE RESOURCES; CHIRAL POLYOLEFINS; PRECISE SYNTHESIS; BLOCK-COPOLYMERS; BAND-GAP;

D O I：

10.1021/ma400067b

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Olefin metathesis has been embraced by polymer chemists as a method for creating well-defined polymers. In particular, ADMET and ROMP have emerged as the primary modes of metathesis polymerization. ADMET reactions are now common, found in textbooks, and easy to perform if the proper techniques are chosen. Much remains to be done, however, with work now focusing on silicon chemistry, direct control of tacticity in precision polymers, biological applications, modeling crystal lattices in common polyolefins, exploring solid-state metathesis reactions, and creating water-soluble ADMET polymers.

引用

页码：4735 / 4741

页数：7

共 103 条

[1] Precise Synthesis of Amphiphilic Multiblock Copolymers by Combination of Acyclic Diene Metathesis (ADMET) Polymerization with Atom Transfer Radical Polymerization (ATRP) and Click Chemistry [J].