Pressure instabilities up to 46 GPa in the relaxor ferroelectric PbZn1/3Nb2/3O3

被引:41
作者
Janolin, P-E [1 ]
Dkhil, B
Bouvier, P
Kreisel, J
Thomas, PA
机构
[1] Ecole Cent Paris, Lab Struct Proprietes & Modelisat Solides, F-92290 Chatenay Malabry, France
[2] CNRS, INPG, Lab Electrochim & Phys Chim Mat & Interfaces, F-38402 St Martin Dheres, France
[3] ENS Phys Grenoble, Lab Mat & Genie Phys, F-38402 St Martin Dheres, France
[4] Univ Warwick, Dept Phys, Coventry CV4 7AL, W Midlands, England
关键词
D O I
10.1103/PhysRevB.73.094128
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We report a high-pressure investigation of the relaxor ferroelectric lead zinc niobate PbZn1/3Nb2/3O3 (PZN) up to 46 GPa, which is the highest pressure yet attained in the study of relaxors. The evolution of both Raman and x-ray scattering with pressure gives evidence for important pressure instabilities, which find its expression in three successive phase transitions. The observed pressure-induced suppression of diffuse scattering above 5 GPa is similar to recent reports and supports the hypothesis that this is a general feature in relaxors at high pressures.
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页数:9
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