Conversion efficiency improvement mechanisms of polymer solar cells by balance electron-hole mobility using blended P3HT:PCBM:pentacene active layer

被引:28
作者
Lee, Ching-Ting [1 ]
Lee, Cheng-Hsin [1 ]
机构
[1] Natl Cheng Kung Univ, Inst Microelect, Dept Elect Engn, Res Ctr Energy Technol & Strategy, Tainan 701, Taiwan
关键词
Blended active layer; Carrier mobility balance; Polymer solar cells; Power conversion efficiency; Space-charge-limited current model; CHARGE-TRANSPORT; POLY(3-HEXYLTHIOPHENE); 3-HEXYLTHIOPHENE;
D O I
10.1016/j.orgel.2013.04.038
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
To improve the power conversion efficiency of polymer solar cells, the blended P3HT:PCBM:pentacene active layer was used to balance hole-electron mobility and roughen surface. Using space-charged-limited current model to analyze the hole-only devices and the electron-only devices, the P3HT: PCBM: pentacene (weight ratio = 1:0.8:0.09) active layer exhibited balance hole-electron mobility. Compared with the power conversion efficiency of 3.46% of the conventional polymer solar cells using P3HT: PCBM (1: 0.8) active layer, the power conversion efficiency of 4.42% was obtained. In other words, the power conversion efficiency was improved about 27.5%. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:2046 / 2050
页数:5
相关论文
共 23 条
[1]   ELECTRICAL-CONDUCTIVITY IN DOPED POLYACETYLENE [J].
CHIANG, CK ;
FINCHER, CR ;
PARK, YW ;
HEEGER, AJ ;
SHIRAKAWA, H ;
LOUIS, EJ ;
GAU, SC ;
MACDIARMID, AG .
PHYSICAL REVIEW LETTERS, 1977, 39 (17) :1098-1101
[2]   Highly stable Ag-Ni based transparent electrodes on PET substrates for flexible organic solar cells [J].
Formica, Nadia ;
Sundar Ghosh, Dhriti ;
Lai Chen, Tong ;
Eickhoff, Christian ;
Bruder, Ingmar ;
Pruneri, Valerio .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2012, 107 :63-68
[3]   Poly(3-hexylthiophene)/C60 heterojunction solar cells:: Implication of morphology on performance and ambipolar charge collection [J].
Geiser, Alain ;
Fan, Bin ;
Benmansour, Hadjar ;
Castro, Fernando ;
Heier, Jakob ;
Keller, Beat ;
Mayerhofer, Karl Emanuel ;
Nueesch, Frank ;
Hany, Roland .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2008, 92 (04) :464-473
[4]   Oxygen doping-induced photogeneration loss in P3HT:PCBM solar cells [J].
Guerrero, Antonio ;
Boix, Pablo P. ;
Marchesi, Luis F. ;
Ripolles-Sanchis, Teresa ;
Pereira, Ernesto C. ;
Garcia-Belmonte, Germa .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2012, 100 :185-191
[5]   Influence of composition and heat-treatment on the charge transport properties of poly(3-hexylthiophene) and [6,6]-phenyl C61-butyric acid methyl ester blends -: art. no. 112105 [J].
Huang, JS ;
Li, G ;
Yang, Y .
APPLIED PHYSICS LETTERS, 2005, 87 (11)
[6]   Polyviologen derivatives as an interfacial layer in polymer solar cells [J].
Jo, Mi Young ;
Ha, Ye Eun ;
Kim, Joo Hyun .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2012, 107 :1-8
[7]   Influence of crystallizable solvent on the morphology and performance of P3HT:PCBM bulk-heterojunction solar cells [J].
Keawprajak, Anusit ;
Piyakulawat, Phimwipha ;
Klamchuen, Annop ;
Iamraksa, Phansak ;
Asawapirom, Udom .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2010, 94 (03) :531-536
[8]   Composition and annealing effects in polythiophene/fullerene solar cells [J].
Kim, Y ;
Choulis, SA ;
Nelson, J ;
Bradley, DDC ;
Cook, S ;
Durrant, JR .
JOURNAL OF MATERIALS SCIENCE, 2005, 40 (06) :1371-1376
[9]  
Lampert M.A., 1970, Current Injection in Solids
[10]   Performance Enhancement of Inverted Polymer Solar Cells Using Roughened Al-Doped ZnO Nanorod Array [J].
Lee, Hsin-Ying ;
Huang, Hung-Lin ;
Lee, Ching-Ting .
APPLIED PHYSICS EXPRESS, 2012, 5 (12)