Squeezing New Life Out of Polymers

被引:16
作者
Brantley, Johnathan N. [1 ,2 ]
Wiggins, Kelly M. [1 ,2 ]
Bielawski, Christopher W. [1 ,2 ]
机构
[1] Univ Texas Austin, Dept Chem & Biochem, Austin, TX 78712 USA
[2] Seoul Natl Univ, Program Chem Convergence Energy & Environm C2E2, World Class Univ, Seoul 151742, South Korea
关键词
catalysts; mechanochemistry; polymers; self-healing materials; sensors;
D O I
10.1002/anie.201210025
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Pressed for results: Mechanical forces can be used to generate reactive small molecules, such as mineral acids and hydrogen peroxide, from appropriately designed polymeric materials. These novel mechanically responsive scaffolds set the foundation for using mechanochemistry to access new classes of self-healing materials and to drive small-scale synthetic reactions. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:3806 / 3808
页数:3
相关论文
共 12 条
[1]  
Baytekin H. T., 2012, ANGEW CHEM, V124, P3656
[2]   Mechanoradicals Created in "Polymeric Sponges" Drive Reactions in Aqueous Media [J].
Baytekin, H. Tarik ;
Baytekin, Bilge ;
Grzybowski, Bartosz A. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (15) :3596-3600
[3]   Ultrasound-induced site-specific cleavage of azo-functionalized poly(ethylene glycol) [J].
Berkowski, KL ;
Potisek, SL ;
Hickenboth, CR ;
Moore, JS .
MACROMOLECULES, 2005, 38 (22) :8975-8978
[4]   Polymer mechanochemistry: the design and study of mechanophores [J].
Brantley, Johnathan N. ;
Wiggins, Kelly M. ;
Bielawski, Christopher W. .
POLYMER INTERNATIONAL, 2013, 62 (01) :2-12
[5]   RETRACTED: Unclicking the Click: Mechanically Facilitated 1,3-Dipolar Cycloreversions (Retracted Article) [J].
Brantley, Johnathan N. ;
Wiggins, Kelly M. ;
Bielawski, Christopher W. .
SCIENCE, 2011, 333 (6049) :1606-1609
[6]   Mechanically-Induced Chemical Changes in Polymeric Materials [J].
Caruso, Mary M. ;
Davis, Douglas A. ;
Shen, Qilong ;
Odom, Susan A. ;
Sottos, Nancy R. ;
White, Scott R. ;
Moore, Jeffrey S. .
CHEMICAL REVIEWS, 2009, 109 (11) :5755-5798
[7]   Proton-Coupled Mechanochemical Transduction: A Mechanogenerated Add [J].
Diesendruck, Charles E. ;
Steinberg, Brian D. ;
Sugai, Naoto ;
Silberstein, Meredith N. ;
Sottos, Nancy R. ;
White, Scott R. ;
Braun, Paul V. ;
Moore, Jeffrey S. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (30) :12446-12449
[8]   Biasing reaction pathways with mechanical force [J].
Hickenboth, Charles R. ;
Moore, Jeffrey S. ;
White, Scott R. ;
Sottos, Nancy R. ;
Baudry, Jerome ;
Wilson, Scott R. .
NATURE, 2007, 446 (7134) :423-427
[9]   Characterizing the mechanochemically active domains in gem-dihalocyclopropanated polybutadiene under compression and tension [J].
Lenhardt, Jeremy M. ;
Black, Ashley L. ;
Beiermann, Brett A. ;
Steinberg, Brian D. ;
Rahman, Faiyam ;
Samborski, Tasha ;
Elsakr, Joseph ;
Moore, Jeffrey S. ;
Sottos, Nancy R. ;
Craig, Stephen L. .
JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (23) :8454-8459
[10]   Trapping a Diradical Transition State by Mechanochemical Polymer Extension [J].
Lenhardt, Jeremy M. ;
Ong, Mitchell T. ;
Choe, Robert ;
Evenhuis, Christian R. ;
Martinez, Todd J. ;
Craig, Stephen L. .
SCIENCE, 2010, 329 (5995) :1057-1060