Lattice approach to the dielectric permittivity of water

被引：11

作者：

Huinink, HP

deKeizer, A

Leermakers, FAM

Lyklema, J

机构：

[1] Department of Physical and Colloid Chemistry, Wageningen Agricultural University, 6703 HB Wageningen

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1996年 / 100卷 / 23期

关键词：

D O I：

10.1021/jp960335w

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A lattice theory, based on a quasi-chemical approach, has been combined with a semimacroscopical theory to calculate the permittivity of water. At low field strength the magnitude and the temperature dependency of the calculated permittivity agree with experimental data. The high-field dielectric behavior of water has also been studied. If the field strength increases, the permittivity goes through a maximum, which has not been found experimentally. This maximum is caused by the fact that orientation of dipoles in the field is strongly cooperative due to hydrogen bonding.

引用

页码：9948 / 9954

页数：7

共 42 条

[1] COMPUTER-SIMULATIONS OF THE DIELECTRIC-PROPERTIES OF WATER - STUDIES OF THE SIMPLE POINT-CHARGE AND TRANSFERABLE INTERMOLECULAR POTENTIAL MODELS [J].