Cyclopropyl compounds as chemical building blocks: Total syntheses of the alkaloids (-)-colchicine, imerubrine and grandirubrine

被引：33

作者：

Banwell, MG ^{[1
]}

机构：

[1] AUSTRALIAN NATL UNIV,RES SCH CHEM,CANBERRA,ACT 0200,AUSTRALIA

来源：

PURE AND APPLIED CHEMISTRY | 1996年 / 68卷 / 03期

关键词：

D O I：

10.1351/pac199668030539

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Fully regio-controlled total syntheses of the title alkaloids (1), (13) and (14) have been developed. In each case, the key step involved acid- or thermally-promoted ring-expansion of the appropriate sigma-homo-o-benzoquinone or sigma-homo-o-benzoquinone monoacetal to generate the troponoid ring associated with the target compounds.

引用

页码：539 / 542

页数：4

共 20 条

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