Alcohol oxidation on nanocrystalline oxide Pd/C promoted electrocatalysts

被引：368

作者：

Shen, PK ^{[1
]}

Xu, CW ^{[1
]}

机构：

[1] Sun Yat Sen Univ, State Key Lab Optoelect Mat & Technol, Sch Phys & Engn, Guangzhou 510275, Guangdong, Peoples R China

来源：

ELECTROCHEMISTRY COMMUNICATIONS | 2006年 / 8卷 / 01期

基金：

中国国家自然科学基金;

关键词：

alcohol oxidation; fuel cell; Pd/C; nanocrystalline oxide; electrocatalyst;

D O I：

10.1016/j.elecom.2005.11.013

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Pd/C promoted with nanocrystalline oxides electrocatalysts were prepared by the intermittent microwave heating. The electrooxidation of methanol, ethanol, glycerol and ethylene glycol on CeO2, Co3O4, Mn3O4 and NiO promoted Pd/C catalysts in alkaline media was studied. Such electrocatalysts are superior to Pt-based electrocatalysts in terms of activity and poison tolerance. The most significant result is that the onset potential for ethanol oxidation on Pd-NiO/C electrocatalyst is shifted negatively by 300 mV compared with that of Pt/C electrocatalyst under the same experimental conditions. The electrochemical parameters were measured and analyzed. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：184 / 188

页数：5

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