Palladium diaqua and hydroxo complexes with polymer-supported BINAP ligands and their use for catalytic enantioselective reactions

被引：51

作者：

Fujii, A ^{[1
]}

Sodeoka, M ^{[1
]}

机构：

[1] Sagami Chem Res Ctr, Sagamihara, Kanagawa 2290012, Japan

来源：

TETRAHEDRON LETTERS | 1999年 / 40卷 / 45期

关键词：

palladium; solid-supported catalysts; enantioselection; aldol reactions; Mannich reactions;

D O I：

10.1016/S0040-4039(99)01663-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

We report the preparation of palladium complexes with the polymer-supported BINAP ligands, [Pd(PS-(R)-binap)(H2O)(2)](2+)(BF4-)(2) (5) and [{Pd(PS-(R)-binap)(mu-OH)}(2)](2+)(BF4-)(2) (9) These complexes were shown to be good catalysts for asymmetric aldol reactions and Mannich-type reactions, and also to be reusable. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：8011 / 8014

页数：4

共 19 条

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