Stabilization of monoclinic SrAl2O4 trough the formation of solid solutions of the type SrAl2-xBxO4

被引:3
作者
Marchal, M [1 ]
Cordoncillo, E
Escribano, P
Vallet-Regí, M
Carda, JB
机构
[1] Univ Jaume 1, UJI, Dept Quim Inorgan, Castellon de La Plana, Spain
[2] Univ Complutense, Fac Farm, Dept Quim Inorgan & Bioinorgan, E-28040 Madrid, Spain
来源
EURO CERAMICS VII, PT 1-3 | 2002年 / 206-2卷
关键词
strontium aluminate; monoclinic structure; solid solution;
D O I
10.4028/www.scientific.net/KEM.206-213.1207
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The aim of this work is to study the synthesis conditions for preparing SrAl2O4 at low temperature and its stabilization as a monclinic form by synthesis of solid solutions of the type SrAl2-xBxO4 (x = 0, 0.1, 0.2, 0.3). The addition of boron can reduce the synthesis temperature of SrAl2O4 because it can provide a liquid medium and increase the diffusion rate and also it can replace the Al (III) ions in the tetrahedral sites of the structure and the distortions caused because of its low ionic radius compared to the aluminium one, could explain the observed reduction in synthesis temperature.
引用
收藏
页码:1207 / 1210
页数:4
相关论文
共 7 条
[1]  
HENDERSON CMB, 1982, MINERAL MAG, P111
[2]   SOLID SOLUBILITY IN SRAL2O4-BAAL2O4 SYSTEM [J].
ITO, S ;
BANNO, S ;
SUZUKI, K ;
INAGAKI, M .
ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-FRANKFURT, 1977, 107 (01) :53-56
[3]   PHASE-TRANSITION IN SRAL2O4 [J].
ITO, S ;
BANNO, S ;
SUZUKI, K ;
INAGAKI, M .
ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-FRANKFURT, 1977, 105 (3-4) :173-178
[4]  
Jolly W.L, 1991, MODERN INORGANIC CHE
[5]  
Levin E. M., 1964, PHASE DIAGRAMS CERAM, V6
[6]  
WEST AR, 1984, SOLID STATE CHEM APP
[7]   THE PREPARATION AND CHARACTERIZATION OF MATERIALS [J].
WOLD, A .
JOURNAL OF CHEMICAL EDUCATION, 1980, 57 (08) :531-536