Zinc(II)- and copper(I)-mediated large two-photon absorption cross sections in a bis-cinnamaldiminato Schiff base

被引:141
作者
Das, S [1 ]
Nag, A [1 ]
Goswami, D [1 ]
Bharadwaj, PK [1 ]
机构
[1] Indian Inst Technol, Dept Chem, Kanpur 208016, Uttar Pradesh, India
关键词
D O I
10.1021/ja056771q
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A Schiff base ligand has been synthesized by condensing 1,2-diaminobenzene with 4-(dimethylamino)cinnamaldehyde to give a donor-π-acceptor-π-donor system which does not show any two-photon absorption cross section but which does, upon complexation with Zn(II) or Cu(I), exhibit very high two-photon absorption cross sections. Copyright © 2006 American Chemical Society.
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页码:402 / 403
页数:2
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