Ruthenium-catalyzed facile aerobic oxidation of α-hydroxycarbonyls to 1,2-dicarbonyl compounds

被引：13

作者：

Chang, S ^{[1
]}

Lee, M

Ko, S

Lee, PH

机构：

[1] Ewha Womans Univ, Dept Chem, Seoul 120750, South Korea

[2] Kangweon Natl Univ, Dept Chem, Chunchon 200701, South Korea

来源：

SYNTHETIC COMMUNICATIONS | 2002年 / 32卷 / 08期

关键词：

D O I：

10.1081/SCC-120003622

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The aerobic oxidation of alpha-hydroxycarbonyl compounds was efficiently carried out with a ruthenium catalyst [RuCl2(p-cymene)](2) in the presence of a catalytic amount of base to afford 1,2-diketones or alpha-ketoesters in good to excellent yields.

引用

页码：1279 / 1284

页数：6

共 11 条

[1]

Buck JS, 1929, J AM CHEM SOC, V51, P2163

[2]

FURNISS BS, 1989, VOGELS TXB PRACTICAL, P1045

[3]

Gill G.B., 1991, Comprehensive Organic Synthesis, VVolume 3, P821

[4] Aerobic oxidation of α-hydroxycarbonyls catalysed by trichlorooxyvanadium:: efficient synthesis of α-dicarbonyl compounds [J].