Dehydration of the nanoporous coordination framework ErIII[CoIII(CN)6]•4(H2O):: single crystal to single crystal transformation and negative thermal expansion in ErIII[CoIII(CN)6]

被引：68

作者：

Pretsch, T ^{[1
]}

Chapman, KW ^{[1
]}

Halder, GJ ^{[1
]}

Kepert, CJ ^{[1
]}

机构：

[1] Univ Sydney, Sch Chem, Sydney, NSW 2006, Australia

来源：

CHEMICAL COMMUNICATIONS | 2006年 / 17期

关键词：

D O I：

10.1039/b601344a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Desorption of bound and unbound water molecules from the nanoporous coordination framework Er-III[ Co-III( CN)(6)]center dot 4H(2)O to form the apohost, Er-III[ Co-III( CN)(6)], proceeds via a single crystal to single crystal transformation in which the Er( III) cations change from 8- to 6-coordinate; dehydration results in a striking change in the thermal expansion properties.

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页码：1857 / 1859

页数：3

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