General and greener route to ketones by palladium-catalyzed direct conversion of carboxylic acids with organoboronic acids

被引：55

作者：

Kakino, R

Narahashi, H

Shimizu, I

Yamamoto, A

机构：

[1] Waseda Univ, Grad Sch Sci & Engn, Dept Appl Chem, Shinjuku Ku, Tokyo 1698555, Japan

[2] Waseda Univ, Adv Res Inst Sci & Engn, Shinjuku Ku, Tokyo 1698555, Japan

来源：

CHEMISTRY LETTERS | 2001年 / 12期

关键词：

D O I：

10.1246/cl.2001.1242

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cross-coupling reaction of carboxylic acids with organoboron compounds catalyzed by palladium complexes in the presence of an activator such as dimethyl dicarbonate under mild conditions gives ketones in excellent yields except for certain substrates.

引用

页码：1242 / 1243

页数：2

共 16 条

[1]

Goossen LJ, 2001, ANGEW CHEM INT EDIT, V40, P3458, DOI 10.1002/1521-3773(20010917)40:18<3458::AID-ANIE3458>3.0.CO

[2]

2-0

[3] Synthesis of trifluoromethyl ketones by palladium-catalyzed cross-coupling reaction of phenyl trifluoroacetate with organoboron compounds [J].