A unique magnesium-based 3D MOF with nanoscale cages and temperature dependent selective gas sorption properties

被引：51

作者：

Huang, Yong-Liang ^{[1
]}

Gong, Yun-Nan ^{[1
]}

Jiang, Long ^{[1
]}

Lu, Tong-Bu ^{[1
]}

机构：

[1] Sun Yat Sen Univ, Sch Chem & Chem Engn, MOE Key Lab Bioinorgan & Synthet Chem, State Key Lab Optoelect Mat & Technol, Guangzhou 510275, Guangdong, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 17期

关键词：

METAL-ORGANIC FRAMEWORK; COORDINATION POLYMER; POROUS FRAMEWORK; UPTAKE CAPACITY; ADSORPTION; CO2; SEPARATION; CATALYSIS; NANOPARTICLES; POLYHEDRA;

D O I：

10.1039/c3cc38730e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A porous Mg-based 3D metal-organic framework with unique nanoscale cages and two-fold interpenetrating pcu nets has been synthesized and characterized. It shows gas-uptake capacities for N-2, H-2, O-2 and CO2 at low temperatures and selective adsorption of CO2 over O-2 and N-2 at room temperature.

引用

页码：1753 / 1755

页数：3

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