Flexible electrostatic nanogenerator using graphene oxide film

被引：80

作者：

Tian, He ^{[1
,2
]}

Ma, Shuo ^{[1
,2
]}

Zhao, Hai-Ming ^{[1
,2
]}

Wu, Can ^{[1
,2
]}

Ge, Jie ^{[1
,2
]}

Xie, Dan ^{[1
,2
]}

Yang, Yi ^{[1
,2
]}

Ren, Tian-Ling ^{[1
,2
]}

机构：

[1] Tsinghua Univ, Inst Microelect, Beijing 100084, Peoples R China

[2] Tsinghua Univ, TNList, Beijing 100084, Peoples R China

来源：

NANOSCALE | 2013年 / 5卷 / 19期

基金：

中国国家自然科学基金;

关键词：

ENERGY HARVESTING CIRCUIT; PIEZOELECTRIC NANOGENERATORS; HIGH-PERFORMANCE; NANOWIRE ARRAYS; SOLAR-CELLS; TRANSISTORS; DEVICES; SUPERCAPACITOR; ELECTRONICS; RESONATORS;

D O I：

10.1039/c3nr01658g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Recently, graphene oxide (GO) super capacitors with ultra-high energy densities have received significant attention. In addition to their use in energy storage, GO capacitors might also have broad applications in renewable energy engineering, such as energy harvesting. Here, a flexible nanogenerator based on GO film is designed. A multilayer structure Al/PI/GO/PI/ITO is made on a flexible PET substrate. The GO nanogenerator could generate a peak voltage of 2 V with a current of 30 nA upon the repetitive application of a 15 N force with a frequency of 1 Hz. Moreover, the output voltage was increased to 34.4 V upon increasing the frequency of force application to 10 Hz. Compared with control samples, embedding GO film with a release structure into the device could significantly enhance the output voltage from 0.1 V to 2.0 V. The mechanism of our nanogenerator can be explained by an electrostatic effect, which is fundamentally different from that of previously reported piezoelectric and triboelectric generators. In this manuscript, we demonstrate flexible nanogenerators with large-area graphene based materials, which may open up new avenues of research with regard to applications in energy harvesting.

引用

页码：8951 / 8957

页数：7

共 45 条

[1] Fabrication and Evaluation of Solution-Processed Reduced Graphene Oxide Electrodes for p- and n-Channel Bottom-Contact Organic Thin-Film Transistors [J].

Becerril, Hector A. ;

Stoltenberg, Randall M. ;

Tang, Ming Lee ;

Roberts, Mark E. ;

Liu, Zunfeng ;

Chen, Yongsheng ;

Kim, Do Hwan ;

Lee, Bang-Lin ;

Lee, Sangyoon ;

Bao, Zhenan .

ACS NANO, 2010, 4 (11) :6343-6352

[2] Energy harvesting vibration sources for microsystems applications [J].

Beeby, S. P. ;

Tudor, M. J. ;

White, N. M. .

MEASUREMENT SCIENCE AND TECHNOLOGY, 2006, 17 (12) :R175-R195

[3] Electromechanical resonators from graphene sheets [J].

Bunch, J. Scott ;

van der Zande, Arend M. ;

Verbridge, Scott S. ;

Frank, Ian W. ;

Tanenbaum, David M. ;

Parpia, Jeevak M. ;

Craighead, Harold G. ;

McEuen, Paul L. .

SCIENCE, 2007, 315 (5811) :490-493

[4] An efficient route to a porous NiO/reduced graphene oxide hybrid film with highly improved electrochromic properties [J].

Cai, Guo-fa ;

Tu, Jiang-ping ;

Zhang, Jun ;

Mai, Yong-jin ;

Lu, Yi ;

Gu, Chang-dong ;

Wang, Xiu-li .

NANOSCALE, 2012, 4 (18) :5724-5730

[5] Graphene Oxide-MnO2 Nanocomposites for Supercapacitors [J].

Chen, Sheng ;

Zhu, Junwu ;

Wu, Xiaodong ;

Han, Qiaofeng ;

Wang, Xin .

ACS NANO, 2010, 4 (05) :2822-2830

[6] High performance of a solid-state flexible asymmetric supercapacitor based on graphene films [J].

Choi, Bong Gill ;

Chang, Sung-Jin ;

Kang, Hyun-Wook ;

Park, Chan Pil ;

Kim, Hae Jin ;

Hong, Won Hi ;

Lee, SangGap ;

Huh, Yun Suk .

NANOSCALE, 2012, 4 (16) :4983-4988

[7] Preparation and characterization of graphene oxide paper [J].

Dikin, Dmitriy A. ;

Stankovich, Sasha ;

Zimney, Eric J. ;

Piner, Richard D. ;

Dommett, Geoffrey H. B. ;

Evmenenko, Guennadi ;

Nguyen, SonBinh T. ;

Ruoff, Rodney S. .

NATURE, 2007, 448 (7152) :457-460

[8]

Eichler A, 2011, NAT NANOTECHNOL, V6, P339, DOI [10.1038/NNANO.2011.71, 10.1038/nnano.2011.71]

[9] Flexible triboelectric generator! [J].

Fan, Feng-Ru ;

Tian, Zhong-Qun ;

Wang, Zhong Lin .

NANO ENERGY, 2012, 1 (02) :328-334

[10] Transparent Triboelectric Nanogenerators and Self-Powered Pressure Sensors Based on Micropatterned Plastic Films [J].

Fan, Feng-Ru ;

Lin, Long ;

Zhu, Guang ;

Wu, Wenzhuo ;

Zhang, Rui ;

Wang, Zhong Lin .

NANO LETTERS, 2012, 12 (06) :3109-3114

← 1 2 3 4 5 →