Structure elucidation of a main heptachloro congener of toxaphene in marine organisms after isolation from Melipax(R)

被引：39

作者：

Krock, B ^{[1
]}

Vetter, W ^{[1
]}

Luckas, B ^{[1
]}

Scherer, G ^{[1
]}

机构：

[1] MAX PLANCK GESSELL AG,ENZYMOL PEPTIDBINDUNG,D-06120 HALLE,GERMANY

来源：

CHEMOSPHERE | 1996年 / 33卷 / 06期

关键词：

D O I：

10.1016/0045-6535(96)00242-1

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

An abundant heptachloro bornane in cod livers, TOX7, has been isolated by repeated high performance liquid chromatography. Its identity was confirmed by GC/MS in the EI and ECNI mode. Larger quantities of TOX7 were isolated from Mehpax(R) and its structure was elucidated by EI mass spectrometry and H-1-NMR measurements as 2-exo, 3-endo, 5-exo, 9, 9, 10, 10-heptachlorobornane. The structural similarity of TOX7 with TOX8 as well as Parlar #41 were discussed. Copyright (C) 1996 Elsevier Science Ltd.

引用

页码：1005 / 1019

页数：15

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