Experimental evidence at atomic resolution of intra- and intermolecular CO•••π(arene) bond interactions

被引：18

作者：

Gambaro, A

Ganis, P

Manoli, F

Polimeno, A

Santi, S

Venzo, A

机构：

[1] CNR, Ctr Studio Stati Mol Radicalici & Eccitati, I-35131 Padua, Italy

[2] Univ Naples Federico II, Dipartimento Chim, I-80134 Naples, Italy

[3] Univ Padua, Dipartimento Chim Fis, I-35131 Padua, Italy

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1999年 / 583卷 / 1-2期

关键词：

unconventional bond interactions; x-ray features; tricarbonylchromium complexes; conformational analysis; ab initio calculations;

D O I：

10.1016/S0022-328X(99)00120-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The crystal data of a number of carbonyl compounds have been reinvestigated. Interactions between carbonyl groups and pi-arene systems have been more deeply discussed from a stereochemical point of view revealing the presence of stabilizing interactions. Preliminar ab initio calculations are in agreement with this interpretation. (C) 1999 Elsevier Science S.A. All rights reserved.

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收藏

页码：126 / 130

页数：5

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