Diarylated Bi(thieno[2,3-c]thiophene)s: A Ring-Fusing Strategy for Controlling the Molecular Alignment of Oligoarenes

被引:27
作者
Fukazawa, Aiko [1 ]
Kishi, Daisuke [1 ]
Tanaka, Yuki [1 ]
Seki, Shu [4 ]
Yamaguchi, Shigehiro [1 ,2 ,3 ]
机构
[1] Nagoya Univ, Grad Sch Sci, Dept Chem, Chikusa Ku, Nagoya, Aichi 4648602, Japan
[2] Nagoya Univ, Inst Transformat Biomol WPI ITbM, Chikusa Ku, Nagoya, Aichi 4648602, Japan
[3] CREST Japan Sci & Technol Agcy JST, Chikusa Ku, Nagoya, Aichi 4648602, Japan
[4] Osaka Univ, Dept Appl Chem, Grad Sch Engn, Suita, Osaka 5650781, Japan
关键词
charge-carrier mobility; oligothiophenes; conjugation; solid-state fluorescence; stacking interactions; GAP CONDUCTING POLYMER; SOLAR-CELLS; ORGANIC SEMICONDUCTORS; CHARGE-TRANSPORT; HOLE MOBILITIES; POLY(ISOTHIANAPHTHENE); PERFORMANCE; POLYTHIOPHENE; EFFICIENCY; OLIGOMERS;
D O I
10.1002/anie.201306323
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Red means go: The dense πstacking of thiophene-fused bithiophene derivatives in the crystalline state led to significantly red-shifted absorption and fluorescence bands (see the photograph of one compound in solution and in the solid state under UV irradiation). The π-stacking structure could be altered by changing the orientation of one of the fused thiophene rings. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:12091 / 12095
页数:5
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