Non-linear optical response of rutile-related oxides, LiM(V)M(VI)O(6), and their derivatives obtained by ion-exchange and intercalation

被引：12

作者：

Bhuvanesh, NSP

Prasad, BR

Subramanian, CK

Gopalakrishnan, J

机构：

[1] INDIAN INST SCI, SOLID STATE & STRUCT CHEM UNIT, BANGALORE 560012, KARNATAKA, INDIA

[2] INDIAN INST SCI, DEPT PHYS, BANGALORE 560012, KARNATAKA, INDIA

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 03期

基金：

美国国家卫生研究院;

关键词：

D O I：

10.1039/cc9960000289

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Polycrystalline samples of oxides of the general formula LiM(V)M(VI)O(6) (M(V) = Nb, Ta; M(VI) = Mo, W), crystallizing in a non-centrosymmetric (space group P (4) over bar 2(1)m) trirutile structure, exhibit second harmonic generation (SHG) of 1064 nm radiation with efficiencies 15-45 times that of alpha-quartz; interestingly, the SHG response is retained by the protonated derivatives HM(V)M(VI)O(6) . xH(2)O, and their n-alkylamine intercalates as well.

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收藏

页码：289 / 290

页数：2

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