Metal-organic co-ordination frameworks based on mixed N- and O-donor ligands:: crystal structures of [Co(phth)2(bipy)] and [Co2(mal)2(bipy)(H2O)2] (phth = phthalate, mal = malonate, bipy=4,4′-bipyridine)

被引：190

作者：

Lightfoot, P ^{[1
]}

Snedden, A ^{[1
]}

机构：

[1] Univ St Andrews, Sch Chem, St Andrews KY16 9ST, Fife, Scotland

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1999年 / 20期

关键词：

D O I：

10.1039/a905726i

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two new metal-organic co-ordination frameworks have been prepared hydrothermally in mixed ligand systems and their crystal structures determined: [Co(phth)(2)(bipy)] is composed of a complex three-dimensional framework consisting of interlinked Co-phth-Co and Co-bipy-Co chains; [Co-2(mal)(2)(bipy)(H2O)(2)] is also three-dimensional, being composed of Co-mal sheets which are pillared by bidentate bipy molecules (phth = phthalate, mal = malonate, bipy = 4,4'-bipyridine). Both frameworks enclose small void channels.

引用

页码：3549 / 3551

页数：3

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