A highly luminescent polymer for LEDs

被引:19
作者
Chuah, BS
Cacialli, F
dos Santos, DA
Feeder, N
Davies, JE
Moratti, SC
Holmes, AB
Friend, RH
Brédas, JL
机构
[1] Univ Cambridge, Melville Lab Polymer Synth, Cambridge CB2 3RA, England
[2] Univ Cambridge, Dept Chem, Cambridge CB2 3RA, England
[3] Univ Cambridge, Cavendish Lab, Cambridge CB3 0HE, England
[4] Univ Mons, Ctr Rech Elect & Photon Mol, B-7000 Mons, Belgium
基金
英国工程与自然科学研究理事会;
关键词
electroluminescence; photoluminescence; light-emitting devices; poly(phenylene vinylene); semiempirical calculations;
D O I
10.1016/S0379-6779(98)00965-5
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A new 2,3-dibutoxy-1,4-phenylene vinylene is reported with high photoluminescence (similar to 40%) and electroluminescence efficiencies. The unusual substitution pattern is effective in tuning the emission colour as the polymer exhibits unexpected blueshifted emission to the green region. Crystal structures of model oligomers (PL efficiencies similar to 80%) and theoretical calculations on optimised geometry offer insight into these interesting properties.
引用
收藏
页码:935 / 936
页数:2
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