All-Oxide Photovoltaics

被引:258
作者
Ruehle, Sven [1 ]
Anderson, Assaf Y. [1 ]
Barad, Hannah-Noa [1 ]
Kupfer, Benjamin [1 ]
Bouhadana, Yaniv [1 ]
Rosh-Hodesh, Eli [1 ]
Zaban, Arie [1 ]
机构
[1] Bar Ilan Univ, Dept Chem, IL-52900 Ramat Gan, Israel
来源
JOURNAL OF PHYSICAL CHEMISTRY LETTERS | 2012年 / 3卷 / 24期
关键词
SENSITIZED SOLAR-CELLS; SPRAY-PYROLYSIS DEPOSITION; DETAILED BALANCE LIMIT; CUPROUS-OXIDE; THIN-FILMS; METAL-OXIDES; CU2O; EFFICIENCY; COMBINATORIAL; TIO2;
D O I
10.1021/jz3017039
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Recently, a new field in photovoltaics (PV) has emerged, focusing on solar cells that are entirely based on metal oxide semiconductors. The all-oxide PV approach is very attractive due to the chemical stability, nontoxicity, and abundance of many metal oxides that potentially allow manufacturing under ambient conditions. Already today, metal oxides (MOs) are widely used as components in PV cells such as transparent conducting front electrodes or electron-transport layers, while only very few MOs have been used as light absorbers. In this Perspective, we review recent developments of all-oxide PV systems, which until today were mostly based on Cu2O as an absorber. Furthermore, ferroelectric BiFeO3-based PV systems are discussed, which have recently attracted considerable attention. The performance of all-oxide PV cells is discussed in terms of general PV principles, and directions for progress are proposed, pointing toward the development of novel metal oxide semiconductors using combinatorial methods.
引用
收藏
页码:3755 / 3764
页数:10
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