A stereoselective total synthesis of the novel sesquiterpene kelsoene

被引：27

作者：

Mehta, G ^{[1
]}

Srinivas, K ^{[1
]}

机构：

[1] Indian Inst Sci, Dept Organ Chem, Bangalore 560012, Karnataka, India

来源：

TETRAHEDRON LETTERS | 1999年 / 40卷 / 26期

关键词：

terpenes; cyclobutene; homologation; Wittig reaction;

D O I：

10.1016/S0040-4039(99)00901-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Employing commercially available 1,5-cyclooctadiene 5 as the starting material, the first total synthesis of the tricyclic sesquiterpene hydrocarbon kelsoene 3 has been accomplished, which also reaffirms its assigned structure. The basic strategy delineated here for the construction of the tricyclo[6.2.0.0(2,6)]decane framework is eminently suitable for the synthesis of other members of this class. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：4877 / 4880

页数：4

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