A simple construction of a rotaxane and pseudorotaxane: Syntheses and X-ray crystal structures of cucurbituril threaded on substituted spermine

被引：77

作者：

Jeon, YM

Whang, D

Kim, J

Kim, K

机构：

[1] POHANG UNIV SCI & TECHNOL, DEPT CHEM, POHANG 790784, SOUTH KOREA

[2] POHANG UNIV SCI & TECHNOL, CTR BIOFUNCT MOL, POHANG 790784, SOUTH KOREA

来源：

CHEMISTRY LETTERS | 1996年 / 07期

关键词：

D O I：

10.1246/cl.1996.503

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A simple, one-step, high-yield synthesis of a rotaxane and pseudorotaxane based on cucurbituril and spermine is presented. Various spectroscopic techniques and X-ray diffraction methods were used to characterize the supramolecular species.

引用

页码：503 / 504

页数：2

共 16 条

[1] MOLECULAR MECCANO .1. [2]ROTAXANES AND A [2]CATENANE MADE TO ORDER [J].

ANELLI, PL ;

ASHTON, PR ;

BALLARDINI, R ;

BALZANI, V ;

DELGADO, M ;

GANDOLFI, MT ;

GOODNOW, TT ;

KAIFER, AE ;

PHILP, D ;

PIETRASZKIEWICZ, M ;

PRODI, L ;

REDDINGTON, MV ;

SLAWIN, AMZ ;

SPENCER, N ;

STODDART, JF ;

VICENT, C ;

WILLIAMS, DJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (01) :193-218

[2]

Behrend R, 1905, LIEBIGS ANN CHEM, V339, P1

[3] STRUCTURES OF THE PARA-XYLYLENEDIAMMONIUM CHLORIDE AND CALCIUM HYDROGENSULFATE ADDUCTS OF THE CAVITAND CUCURBITURIL, C36H36N24O12 [J].

FREEMAN, WA .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1984, 40 (AUG) :382-387

[4] CUCURBITURIL [J].

FREEMAN, WA ;

MOCK, WL ;

SHIH, NY .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (24) :7367-7368

[5] PREPARATION AND CHARACTERIZATION OF A POLYROTAXANE CONSISTING OF MONODISPERSE POLY(ETHYLENE GLYCOL) AND ALPHA-CYCLODEXTRINS [J].

HARADA, A ;

LI, J ;

KAMACHI, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (08) :3192-3196

[6] THE MOLECULAR NECKLACE - A ROTAXANE CONTAINING MANY THREADED ALPHA-CYCLODEXTRINS [J].

HARADA, A ;

LI, J ;

KAMACHI, M .

NATURE, 1992, 356 (6367) :325-327

[7] NOVEL CLASS OF ASYMMETRIC ZWITTERIONIC ROTAXANES BASED ON ALPHA-CYCLODEXTRIN [J].

ISNIN, R ;

KAIFER, AE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (21) :8188-8190

[8] DYNAMICS OF MOLECULAR RECOGNITION INVOLVING CUCURBITURIL [J].

MOCK, WL ;

SHIH, NY .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (07) :2697-2699

[9] STRUCTURE AND SELECTIVITY IN HOST GUEST COMPLEXES OF CUCURBITURIL [J].

MOCK, WL ;

SHIH, NY .

JOURNAL OF ORGANIC CHEMISTRY, 1986, 51 (23) :4440-4446

[10] ORGANIC LIGAND RECEPTOR INTERACTIONS BETWEEN CUCURBITURIL AND ALKYLAMMONIUM IONS [J].

MOCK, WL ;

SHIH, NY .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (14) :4706-4710

← 1 2 →