Diastereoselective formation of cyclic acetals via an intramolecular fluoride-catalyzed hetero-Michael reaction

被引：9

作者：

Evans, PA

Garber, LT

机构：

[1] Lammot du Pont Laboratory, Dept. of Chemistry and Biochemistry, University of Delaware, Newark

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 17期

关键词：

D O I：

10.1016/0040-4039(96)00449-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Treatment of the tert-butyldimethylsilyl ethers 1a-g with tetra-N-butylammonium fluoride furnished the corresponding cyclic acetals 2/3a-g in 82-90% yield and with excellent diastereoselectivity for n = 1 and 2. (C) 1996 Elsevier Science Ltd

引用

页码：2927 / 2930

页数：4

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