Functionalization of saturated hydrocarbons by aprotic superacids .5. Regioselective carbonylation of propane in an organic solvent initiated by aprotic organic superacids CX(4)center dot nAlBr(3) (X=Br,Cl; n=1 or 2)

被引:13
作者
Akhrem, IS
Orlinkov, AV
Afanaseva, LV
Volpin, ME
机构
[1] A. N. Nesmeyanov Inst. O., Russian Academy of Sciences, 117813 Moscow
关键词
propane; carbonylation; carbon monoxide; aprotic superacids; polyhalomethanes; aluminum bromide;
D O I
10.1007/BF01431610
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Aprotic organic superacids CX(4) . nAlBr(3) (X = Br, Cl; n = 1 or 2) are effective initiators of carbonylation of propane with CO in an organic solvent at -10 to -20 degrees C.
引用
收藏
页码:1154 / 1156
页数:3
相关论文
共 18 条
[1]   A NOVEL FAMILY OF APROTIC ORGANIC SUPERACIDS FOR LOW-TEMPERATURE ALKANE AND CYCLOALKANE TRANSFORMATIONS [J].
AKHREM, I ;
ORLINKOV, A ;
VOLPIN, M .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (08) :671-672
[2]  
AKHREM I, 1996, IN PRESS CHEM A EURO
[3]   Functionalization of saturated hydrocarbons by aprotic superacids .4. Ionic bromination of ethane and other alkanes and cycloalkanes with molecular bromine in the presence of systems based on polyhalomethanes and AlBr3 under mild conditions [J].
Akhrem, IS ;
Orlinkov, AV ;
Afanaseva, LV ;
Volpin, ME .
RUSSIAN CHEMICAL BULLETIN, 1996, 45 (05) :1148-1153
[4]  
AKHREM IS, 1993, MENDELEEV COMMUN, P188
[5]  
AKHREM IS, 1994, MENDELEEV COMMUN, P131
[6]  
AKHREM IS, 1996, IN PRESS TETRAHEDRON
[7]  
BERNADYUK SZ, 1994, MENDELEEV COMMUN, P185
[8]   SELECTIVE CARBONYLATION OF PROPANE IN HF-SBF5 - THE ROLE OF CARBON-MONOXIDE IN THE HALOGEN-PROMOTED ACTIVATION STEP [J].
BUKALA, J ;
CULMANN, JC ;
SOMMER, J .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (06) :481-483
[9]   Electronic structure, geometry, and stability of organic cations, dications, and donor-acceptor complexes .2. Polyhalomethane complexes with aluminum halides [J].
Chistyakov, AL ;
Stankevich, IV ;
Akhrem, IS ;
Gambaryan, NP ;
Volpin, ME .
RUSSIAN CHEMICAL BULLETIN, 1996, 45 (03) :514-520
[10]   SELECTIVE CARBONYLATION OF PROPANE IN SUPERACID MEDIA VIA HYDRIDE ABSTRACTION BY THE CHLOROCARBOCATIONS - CCL3+ AND CHCL2+ [J].
CULMANN, JC ;
SIMON, M ;
SOMMER, J .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (16) :1098-1101