Study of the corrosion resistance of Cr, Zr, Y doped AB5 type alloys in KOH

被引:9
作者
Arnaud, O
Barbic, P
Bernard, P
Bouvier, A
Knosp, B
Riegel, B
Wohlfahrt-Mehrens, M
机构
[1] SAFT, Direct Rech, F-33074 Bordeaux, France
[2] Treibacher Auermet, A-9330 Treibach Althofen, Austria
[3] ZSW, D-89081 Ulm, Germany
关键词
AB(5) type alloys; Cr; Zr; Y; corrosion resistance;
D O I
10.1016/S0925-8388(01)01671-1
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The effect of partial substitutions of Y, Zr or Cr on the chemical stability of AB(5+x) alloys in concentrated KOH aqueous solution was investigated. Alloys were elaborated using conventional casting, rapid cooling or gas atomisation, then heat-treated and characterised in terms of chemical composition, microstructure (MEB, XRD), electrochemical performances and corrosion resistance in a 8.7 M KOH solution at 70degreesC. Single phase alloys were obtained using Y or Cr as additive. Among them, superstoichiometric Cr alloys exhibited improved corrosion resistance during soaking tests. (C) 2002 Elsevier Science BY All rights reserved.
引用
收藏
页码:262 / 267
页数:6
相关论文
共 10 条
[1]  
Cocciantelli JM, 1999, J NEW MAT ELECT SYST, V2, P151
[2]   The influence of Co and various additives on the performance of MmNi(4.3-x)Mn(0.33)Al(0.4)Co(x) hydrogen storage alloys and Ni/MH prismatic sealed cells [J].
Cocciantelli, JM ;
Bernard, P ;
Fernandez, S ;
Atkin, J .
JOURNAL OF ALLOYS AND COMPOUNDS, 1997, 253 :642-647
[3]  
FURUKAWA K, 1997, YUASA JIHO, V82, P27
[4]  
HAZAMA, 1991, Patent No. 0451575
[5]  
KAIA H, 1995, J ALLOY COMPD, V231, P598
[6]   CYCLIC BEHAVIOR OF METAL HYDRIDE ELECTRODES AND THE CELL CHARACTERISTICS OF NICKEL METAL HYDRIDE BATTERIES [J].
KANDA, M ;
YAMAMOTO, M ;
KANNO, K ;
SATOH, Y ;
HAYASHIDA, H ;
SUZUKI, M .
JOURNAL OF THE LESS-COMMON METALS, 1991, 172 :1227-1235
[7]   Mechanism of alloy corrosion and consequences an sealed nickel-metal hydride battery performance [J].
Leblanc, P ;
Jordy, C ;
Knosp, B ;
Blanchard, P .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1998, 145 (03) :860-863
[8]   ON THE NATURE OF THE ELECTROCHEMICAL CYCLING STABILITY OF NONSTOICHIOMETRIC LANI5-BASED HYDRIDE-FORMING COMPOUNDS .1. CRYSTALLOGRAPHY AND ELECTROCHEMISTRY [J].
NOTTEN, PHL ;
EINERHAND, REF ;
DAAMS, JLC .
JOURNAL OF ALLOYS AND COMPOUNDS, 1994, 210 (1-2) :221-232
[9]   METAL HYDRIDE ANODES FOR NICKEL-HYDROGEN SECONDARY BATTERY [J].
SAKAI, T ;
MIYAMURA, H ;
KURIYAMA, N ;
KATO, A ;
OGURO, K ;
ISHIKAWA, H .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1990, 137 (03) :795-799
[10]  
WILLEMS JJG, 1984, PHILIPS J RES S1, V39