Physicomechanical properties of nanocomposites based on cellulose nanofibre and natural rubber latex

被引：167

作者：

Abraham, Eldho ^{[1
,2
,3
]}

Deepa, B. ^{[2
]}

Pothan, L. A. ^{[2
]}

John, Maya ^{[4
]}

Narine, S. S. ^{[1
]}

Thomas, S. ^{[3
]}

Anandjiwala, R. ^{[4
]}

机构：

[1] Trent Univ, Trent Biomat Res Program, Peterborough, ON K9J 7B8, Canada

[2] Bishop Moore Coll, Dept Chem, Mavelikkara 690101, Kerala, India

[3] Mahatma Gandhi Univ, Sch Chem Sci, Kottayam 686560, Kerala, India

[4] CSIR, Polymers & Composites Competence Area, Mat Sci & Mfg, Port Elizabeth, South Africa

来源：

CELLULOSE | 2013年 / 20卷 / 01期

关键词：

Bionanocomposites; Fibre/matrix bond; Thermomechanical properties; Natural rubber; Nanocellulose; Zn-cellulose complex; MECHANICAL-PROPERTIES; FILLER; COMPOSITES; FIBERS; NR;

D O I：

10.1007/s10570-012-9830-1

中图分类号：

TB3 [工程材料学]; TS [轻工业、手工业、生活服务业];

学科分类号：

082905 [生物质能源与材料]; 140303 [工业设计];

摘要：

Cellulose nanofibres (CNF) with diameter 10-60 nm were isolated from raw banana fibres by steam explosion process. These CNF were used as reinforcing elements in natural rubber (NR) latex along with cross linking agents to prepare nanocomposite films. The effect of CNF loading on the mechanical and dynamic mechanical (DMA) properties of NR/CNF nanocomposite was studied. The morphological, crystallographic and spectroscopic changes were also analyzed. Significant improvement of Young's modulus and tensile strength was observed as a result of addition of CNF to the rubber matrix especially at higher CNF loading. DMA showed a change in the storage modulus of the rubber matrix upon addition of CNF which proves the reinforcing effect of CNF in the NR latex. A mechanism is suggested for the introduction of the Zn-cellulose complex and its three dimensional network as a result of the reaction between the cellulose and the Zinc metal which is originated during the composite formation.

引用

页码：417 / 427

页数：11

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