A combined covalent and coordination approach to dendritic multiporphyrin arrays based on ruthenium(II) porphyrins

被引:59
作者
Darling, SL
Mak, CC
Bampos, N
Feeder, N
Teat, SJ
Sanders, JKM
机构
[1] Univ Cambridge, Cambridge Ctr Mol Recognit, Chem Lab, Cambridge CB2 1EW, England
[2] CLRC, Daresbury Lab, Warrington WA4 4AD, Cheshire, England
关键词
D O I
10.1039/a900344d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Two strategies have been employed in the construction of multiporphyrin arrays; the principles are illustrated by a seven-porphyrin array consisting of two three-porphyrin dendrons coordinated to a single ruthenium(II) porphyrin, and by a six-porphyrin array containing three ruthenium(I) porphyrin monomers coordinated to a tripyridyl porphyrin trimer. These systems possess both redox and photophysical functionality built-in to the overall structure.
引用
收藏
页码:359 / 364
页数:6
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