Evolution of protonic conduction in [Zn-Al-Cl] Lamellar Double Hydroxide phases with temperature and trivalent metal content

被引：15

作者：

Ducos, V ^{[1
]}

de Roy, A ^{[1
]}

Besse, JP ^{[1
]}

机构：

[1] Univ Clermont Ferrand, Univ Blaise Pascal, Lab Mat Inorgan, UMR CNRS 6002, F-63177 Clermont Ferrand, France

来源：

SOLID STATE IONICS | 2001年 / 145卷 / 1-4期

关键词：

lamellar; hydroxide; LDH; anionic clay; protonic conduction; impedance spectroscopy; X-ray diffraction; structure;

D O I：

10.1016/S0167-2738(01)00936-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The conduction properties of a series of [Zn-Al-Cl] Lamellar Double Hydroxides (LDHs) with different amounts of trivalent metal are studied by impedance spectroscopy. The structural evolution of these samples is characterized by Rietveld analysis on powder X-ray diffraction diagrams. The conduction properties appear clearly related to the structural evolution of the interlayer domains. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：399 / 405

页数：7

共 16 条

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