An α-Keggin polyoxometalate completely constructed from the late transition metal CoII as poly atom

被引：18

作者：

Dong, Lanjun ^{[1
]}

Li, Xiaofang ^{[1
]}

Cao, Jie ^{[1
]}

Chu, Wei ^{[1
]}

Huang, Rudan ^{[1
]}

机构：

[1] Beijing Inst Technol, Key Lab Cluster Sci, Minist Educ, Sch Chem, Beijing 100081, Peoples R China

来源：

DALTON TRANSACTIONS | 2013年 / 42卷 / 05期

基金：

北京市自然科学基金;

关键词：

CLUSTERS; CENTERS; NANOSTRUCTURES;

D O I：

10.1039/c2dt31896b

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

We report a catalytic eight-cobalt-capped alpha-Keggin polyoxoazocobaltite with a highly symmetric structure completely constructed from the late transition-metal Co-II as a poly atom, [Co-20(OH)(24)(MMT)(12)(SO4)](NO3)(2)center dot 6H(2)O (1) (MMT: 2-mercapto-5-methyl-1,3,4-thiadiazole). To the best of our knowledge, this is the first homometallic Co-II magnetic cluster bearing Keggin structure. It can serve as a potential catalyst in the styrene polymerization.

引用

页码：1342 / 1345

页数：4

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