Facile syntheses of tris(trifluoromethyl)phosphine and difluorotris(trifluoromethyl)phosphorane

被引：15

作者：

Gorg, M

Roschenthaler, GV

Kolomeitsev, AA

机构：

[1] UNIV BREMEN,INST INORGAN & PHYS CHEM,D-28334 BREMEN,GERMANY

[2] UKRAINIAN ACAD SCI,INST ORGAN CHEM,UA-252660 KIEV,UKRAINE

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1996年 / 79卷 / 01期

关键词：

tris(trifluoromethyl)phosphine; hexaethylphosphorus triamide; bromotrifluoromethane; triphenylphosphite; zinc difluoride; difluorotris(trifluoromethyl)-phosphorane;

D O I：

10.1016/0022-1139(96)03471-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Tris (trifluoromethyl) phosphine is easily available in high yield using the three component system P(NEt)(2))(3)/CF3Br/(PhO)(3)P in HMPA. Addition of chlorine and fluorination with zinc difluoride yield difluorotris(trifluoromethyl) phosphorane.

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收藏

页码：103 / 104

页数：2

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