Syntheses and characterization of the samarium(III)-copper(II) 3D coordination network constructed by iminodiacetic acid

被引：22

作者：

Cai, YP ^{[1
]}

Li, GB

Zhan, QG

Sun, F

Zhang, JG

Gao, S

Xu, AW

机构：

[1] S China Normal Univ, Dept Chem, Guangzhou 510631, Peoples R China

[2] S China Normal Univ, Sch Phys & Telecommun Engn, Guangzhou 510631, Peoples R China

[3] Sun Yet Sen Univ, Sch Chem & Chem Engn, Guangzhou 510275, Peoples R China

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 2005年 / 178卷 / 12期

关键词：

lanthanide(III)-copper(II) coordination polymers; iminodiacetic acid; crystal structures; temperature-dependent magnetic susceptibilities; the thermal stabilities;

D O I：

10.1016/j.jssc.2005.09.033

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The hydrothermal reaction of Sm2O3 with iminodiacetic acid (H(2)1dad), CuO, and H2O with a mole ratio of 1:2:4:300 resulted in the formation of one nanoporous 3D open framework Cu(II)-Sm(III) coordination polymer, [Sm2Cu3(Idad)(6)} center dot 8H(2)O](n). Investigation shows that the coordination polymer possesses high thermal and structural stability. temperature-dependent magnetic susceptibilities of the coordination polymer with the similar structure, [{Gd2Cu3(Idad)(6)} center dot 8H(2)O](n), were studied. (C) 2005 Elsevier Inc. All rights reserved.

引用

页码：3729 / 3734

页数：6

共 38 条

[1]

[Anonymous], 1996, SADABS PROGRAM SCALI

[2] Formation of racemate and mesocate complexes from an achiral tripodal ligand containing three benzimidazole groups [J].

Cai, YP ;

Su, CY ;

Chen, CL ;

Li, YM ;

Kang, BS ;

Chan, ASC ;

Kaim, W .

INORGANIC CHEMISTRY, 2003, 42 (01) :163-168

[3] A chemically functionalizable nanoporous material [Cu3(TMA)2(H2O)3]n [J].

Chui, SSY ;

Lo, SMF ;

Charmant, JPH ;

Orpen, AG ;

Williams, ID .

SCIENCE, 1999, 283 (5405) :1148-1150

[4] [Cu(pyrazine-2-carboxylate)2]2Cd4I8:: unprecedented 1-D serpentine inorganic chains and regular 2-D metal-organic square grids in a 3-D framework [J].

Ciurtin, DM ;

Smith, MD ;

zur Loye, HC .

CHEMICAL COMMUNICATIONS, 2002, (01) :74-75

[5]

Doble DMJ, 1999, ANGEW CHEM INT EDIT, V38, P1915, DOI 10.1002/(SICI)1521-3773(19990712)38:13/14<1915::AID-ANIE1915>3.0.CO

[6]

2-L

[7] Novel water clusters in the crystalline state: structures of a symmetrical, cyclic hexamer and an 'opened-cube' octamer [J].

Doedens, RJ ;

Yohannes, E ;

Khan, MI .

CHEMICAL COMMUNICATIONS, 2002, (01) :62-63

[8]

Dong YB, 2000, ANGEW CHEM INT EDIT, V39, P4271, DOI 10.1002/1521-3773(20001201)39:23<4271::AID-ANIE4271>3.0.CO

[9]

2-1

[10]

EDDAOUDI M, 2001, ACCOUNTS CHEM RES, V34, P133

← 1 2 3 4 →