Nucleobase-containing transition metal complexes as building blocks for biological markers and supramolecular structures

被引:26
作者
Lynam, Jason M. [1 ]
机构
[1] Univ York, Dept Chem, York YO10 5DD, N Yorkshire, England
关键词
D O I
10.1039/b802347f
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The incorporation of metal complexes into nucleobases, nucleosides and nucleotides has provided a focus for the development of many novel compounds with a wide range of applications. In this perspective article the different methods to incorporate transition metal complexes into these species will be described. Applications of these compounds as biological markers, catalysts and how the hydrogen bonding properties may be employed in directing supramolecular assembly in both the solid state and solution will be discussed.
引用
收藏
页码:4067 / 4078
页数:12
相关论文
共 57 条
[11]   Labeling of organic biomolecules with ethynylferrocene [J].
Coutouli-Argyropoulou, E ;
Tsitabani, M ;
Petrantonakis, G ;
Terzis, A ;
Raptopoulou, C .
ORGANIC & BIOMOLECULAR CHEMISTRY, 2003, 1 (08) :1382-1388
[12]  
Cowley MJ, 2007, DALTON T, P4427, DOI 10.1039/b709483c
[13]  
COWLEY MJ, UNPUB
[14]   PALLADIUM-CATALYZED COUPLING OF TERMINAL ALKYNES WITH 5-(TRIFLUOROMETHANESULFONYLOXY)PYRIMIDINE NUCLEOSIDES [J].
CRISP, GT ;
FLYNN, BL .
JOURNAL OF ORGANIC CHEMISTRY, 1993, 58 (24) :6614-6619
[15]  
DAVIES SG, 1991, ADV ORGANOMET CHEM, V30, P1
[16]   Synthesis of dicobalt hexacarbonyl 5-p-tolylethynyl-2′-deoxyuridine [J].
Esho, N ;
Davies, B ;
Lee, J ;
Dembinski, R .
CHEMICAL COMMUNICATIONS, 2002, (04) :332-333
[17]  
Fillaut JL, 2002, EUR J INORG CHEM, P935
[18]   Sonogashira alkynylation of unprotected 8-brominated adenosines and guanosines: fluorescence properties of compact conjugated acetylenes containing a purine ring [J].
Firth, Andrew G. ;
Fairlamb, Ian J. S. ;
Darley, Kate ;
Baumann, Christoph G. .
TETRAHEDRON LETTERS, 2006, 47 (21) :3529-3533
[19]   Bioorganometallic chemistry:: synthesis, structure, and molecular recognition chemistry of (η5-pentamethylcyclopentadienyl)-rhodium-DNA/RNA complexes in water [J].
Fish, RH .
COORDINATION CHEMISTRY REVIEWS, 1999, 185-6 :569-584
[20]   Bioorganometallic chemistry: Structural diversity of organometallic complexes with bioligands and molecular recognition studies of several supramolecular hosts with biomolecules, alkali-metal ions, and organometallic pharmaceuticals [J].
Fish, RH ;
Jaouen, G .
ORGANOMETALLICS, 2003, 22 (11) :2166-2177