A new generation of nickel-dmit-based molecular conductors based on fully conjugated bimetallic complexes

被引：31

作者：

Pullen, AE

Olk, RM

Zeltner, S

Hoyer, E

Abboud, KA

Reynolds, JR

机构：

[1] UNIV FLORIDA, DEPT CHEM, CTR MACROMOL SCI & ENGN, GAINESVILLE, FL 32611 USA

[2] UNIV LEIPZIG, INST ANORGAN CHEM, D-04103 LEIPZIG, GERMANY

来源：

INORGANIC CHEMISTRY | 1997年 / 36卷 / 06期

关键词：

D O I：

10.1021/ic9610389

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

We report the synthesis of a new completely planar, extensively conjugated bimetallic Ni(II) complex for the construction of new molecular metals. The complex, (Bu(4)N)(2) {tto[Ni9dmit)](2)} (1), with 14 sulfur atoms in the periphery, has Ni(II) metal centers bridged by the tetrthiooxalate (tto) ligand and capped with dmit (dmit=C3S52-=2-thioxo-1,3-dithiole-4,5-dithiolato) ligands. This is the first completely planar complex with tto bridging Ni(II) metal centers. Reation of 1 with (TTF)(3)-(BF4)(2) forms a conducting material with a high pressed-pellet conductivity of 0.4 s/cm.

引用

页码：958 / +

页数：3

共 32 条

[1] HIGHLY CONDUCTING CHARGE-TRANSFER COMPOUNDS OF TETRATHIAFULVALENE AND TRANSITION-METAL DMIT COMPLEXES [J].