Kharasch addition and controlled atom transfer radical polymerisation (ATRP) of vinyl monomers catalysed by Grubbs' ruthenium-carbene complexes

被引：103

作者：

Simal, F ^{[1
]}

Demonceau, A ^{[1
]}

Noels, AF ^{[1
]}

机构：

[1] Univ Liege, Macromol Chem & Organ Catalysis Lab, B-4000 Cointe Ougree, Belgium

来源：

TETRAHEDRON LETTERS | 1999年 / 40卷 / 31期

关键词：

catalysis; olefins; radicals; radical reactions; ruthenium; ruthenium compounds;

D O I：

10.1016/S0040-4039(99)01090-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The Grubbs' ruthenium-carbene complexes, RuCl2(=CHPh)(PR3)(2), mediate the Kharasch addition of CCl4 across olefins, and the controlled atom transfer radical polymerisation of vinyl monomers with high yields and selectivities which markedly depend on the phosphine ligands of the complex (R=phenyl, cyclopentyl, and cyclohexyl). (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：5689 / 5693

页数：5

共 12 条

[1] Design of initiators for living radical polymerization of methyl methacrylate mediated by ruthenium(II) complex [J].

Ando, T ;

Kamigaito, M ;

Sawamoto, M .

TETRAHEDRON, 1997, 53 (45) :15445-15457

[2] POLYMERIZATION OF METHYL-METHACRYLATE WITH THE CARBON-TETRACHLORIDE DICHLOROTRIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II) METHYLALUMINUM BIS(2,6-DI-TERT-BUTYLPHENOXIDE) INITIATING SYSTEM - POSSIBILITY OF LIVING RADICAL POLYMERIZATION [J].

KATO, M ;

KAMIGAITO, M ;

SAWAMOTO, M ;

HIGASHIMURA, T .

MACROMOLECULES, 1995, 28 (05) :1721-1723

[3]

Perrin D.D., 1980, PURIFICATION LAB CHE, VSecond

[4]

SAWAMOTO M, 1999, MAT SCI TECHNOLOGY S, P163

[5]

Simal F, 1999, ANGEW CHEM INT EDIT, V38, P538, DOI 10.1002/(SICI)1521-3773(19990215)38:4<538::AID-ANIE538>3.0.CO

[6]

2-W

[7]

SIMAL F, 1998, 11 INT S HOM CAT ISH

[8]

SIMAL F, 1999, ANGEW CHEM, V111, P559

[9] New reactivity from (PCy3)2Cl2Ru=CHPh:: A mild catalyst for Kharasch additions [J].

Tallarico, JA ;

Malnick, LM ;

Snapper, ML .

JOURNAL OF ORGANIC CHEMISTRY, 1999, 64 (02) :344-345

[10] Mechanistic aspects of the Kharasch addition reaction catalyzed by organonickel(II) complexes containing the monoanionic terdentate arlydiamine ligand system [C6H2(CH2NMe2)(2)-2,6-R-4] [J].

vandeKuil, LA ;

Grove, DM ;

Gossage, RA ;

Zwikker, JW ;

Jenneskens, LW ;

Drenth, W ;

vanKoten, G .

ORGANOMETALLICS, 1997, 16 (23) :4985-4994

← 1 2 →