Anodic oxidation of hexamethoxybiphenyls into either stable cation radical salt or spiro(fluorene-9,1'-cyclohexadienones)

被引：7

作者：

Douadi, T ^{[1
]}

Cariou, M ^{[1
]}

Simonet, J ^{[1
]}

机构：

[1] UNIV CATHOLIQUE OUEST,URA CNRS 439,LAB ELECTROCHIM ORGAN,F-49008 AUGERS 01,FRANCE

来源：

TETRAHEDRON | 1996年 / 52卷 / 12期

关键词：

D O I：

10.1016/0040-4020(96)00134-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Three symmetrically substituted hexamethoxybiphenyls were subjected to electrooxidation at a platinum anode. 2,2',4,4',5,5'-hexamethoxybiphenyl led to the stable cation radical salt expected, whereas 3,3',4,4',5,5'-hexamethoxybiphenyl and 2,2',3,3',4,4'-hexamethoxybiphenyl afforded unexpected spiro(fluorene-9,1'-cyclohexadienones).

引用

页码：4449 / 4456

页数：8

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