Synthesis of functionalised diarylmethanes via a cobalt-catalysed cross-coupling of arylzinc species with benzyl chlorides

被引:84
作者
Amatore, Muriel [1 ]
Gosmini, Corinne [2 ]
机构
[1] Univ Paris 12, CNRS, Equipe Electrochim & Synth Organ, Inst Chim & Mat Paris Est,ICMPE,UMR 7182, F-94320 Thiais, France
[2] Ecole Polytech, CNRS, Lab Heteroelements & Coordinat, F-91128 Palaiseau, France
关键词
D O I
10.1039/b809626k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new cobalt-catalysed reductive coupling of aryl halides with benzyl chlorides is reported; a variety of diarylmethanes can be prepared in good to excellent yields under mild reaction conditions using CoBr2 as catalyst and Zn dust; this new cobalt-catalysed coupling represents a practical and interesting alternative to previously known methods for the synthesis diarylmethanes.
引用
收藏
页码:5019 / 5021
页数:3
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