Isolation and structural characterization of novel compounds containing B4O2 rings

被引：25

作者：

Carmalt, CJ

Clegg, W

Cowley, AH

Lawlor, FJ

Marder, TB

Norman, NC

Rice, CR

Sandoval, OJ

Scott, AJ

机构：

[1] UNIV TEXAS, DEPT CHEM & BIOCHEM, AUSTIN, TX 78712 USA

[2] UNIV NEWCASTLE UPON TYNE, DEPT CHEM, NEWCASTLE UPON TYNE NE1 7RU, TYNE & WEAR, ENGLAND

[3] UNIV BRISTOL, SCH CHEM, BRISTOL BS8 1TS, AVON, ENGLAND

[4] UNIV WATERLOO, DEPT CHEM, WATERLOO, ON N2L 3G1, CANADA

来源：

POLYHEDRON | 1997年 / 16卷 / 13期

基金：

加拿大自然科学与工程研究理事会; 英国工程与自然科学研究理事会;

关键词：

boron; diboron; X-ray; inorganic ring; cyclic; tetraboron;

D O I：

10.1016/S0277-5387(96)00559-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two compounds containing planar six-membered B4O2 rings have been synthesized and characterized by X-ray crystallography, namely [B4O2(OH)(4)].[NH2Me2][Cl] and [B4O2(dab)(2)] (dab = 1,4-Bu-t-1,4-diazabutadiene), the former compound providing a model for one possible structure of boron monoxide. {BO}(x). (C) 1997 Elsevier Science Ltd.

引用

页码：2325 / 2328

页数：4

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