Hydrothermal synthesis and characterization of a new layered gallophosphate JGP-L1 with a Ga/P ratio of non-unity

被引：9

作者：

Yang, YL

Liu, YL

Mu, ZC

Ye, L

Hu, T

Chen, C

Pang, WQ ^{[1
]}

机构：

[1] Jilin Univ, Coll Chem, Dept Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130023, Peoples R China

[2] Jilin Univ, Coll Chem, Minist Educ, Key Lab Supramol Struct & Mat, Changchun 130023, Peoples R China

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 2004年 / 177卷 / 03期

基金：

中国国家自然科学基金;

关键词：

synthesis; characterization; layered gallophosphate; tetraethyleneperitamine; extremely low reactional concentration;

D O I：

10.1016/j.jssc.2003.08.034

中图分类号：

O61 [无机化学];

学科分类号：

070301 [无机化学]; 081704 [应用化学];

摘要：

A new compound, Ga-6(OH)(4)(HPO4)(2)(PO4)(5) . C8H28N5.3H(2)O (denoted JGP-L1), with a gallophosphate layer and a Ga/P ratio of 6,17 has been synthesized hydrothermally by using tetraethylenepentamine as template. It is characterized by powder X-ray diffraction (XRD), elemental analysis, inductively coupled plasma, and TGA analysis and structurally determined by single-crystal XRD analysis. JGP-L1 crystallizes in the orthorhombic, space group Pna2(1) (no. 33), with a = 16.422(3) b = 11.898(2), c = 18.730(4) Angstrom, V = 3659.6(13)Angstrom(3) and Z = 4. The structure of JGP-L1 is built tip by alternating of Ga(OH)(2)O-4 octahedra, Ga(OH)04 trigonal bipyramids and PO4 (or HPO4) tetrahedra to form inorganic sheets. It is noteworthy that JGP-L1 was synthesized with extremely low reactant concentration. where the reaction mixture exhibits a H2O:Ga2O3 molar ratio of 2220:1. (C) 2003 Elsevier Inc. All rights reserved.

引用

页码：696 / 700

页数：5

共 20 条

[1]

SYNTHESIS AND STRUCTURE OF A NOVEL MICROPOROUS GALLOPHOSPHATE, NA3GA5(PO4)(4)O-2(OH)(2)CENTER-DOT-2H(2)O [J].

ATTFIELD, MP ;

MORRIS, RE ;

GUTIERREZPUEBLA, E ;

MONGEBRAVO, A ;

CHEETHAM, AK .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (08) :843-844

[2]

MIL-50, an open-framework GaPO with a periodic pattern of small water ponds and dry rubidium atoms:: a combined XRD, NMR, and computational study [J].

Beitone, L ;

Marrot, J ;

Loiseau, T ;

Férey, G ;

Henry, M ;

Huguenard, C ;

Gansmuller, A ;

Taulelle, F .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (07) :1912-1922

[3]

Cheetham AK, 1999, ANGEW CHEM INT EDIT, V38, P3268, DOI 10.1002/(SICI)1521-3773(19991115)38:22<3268::AID-ANIE3268>3.0.CO

[4]

2-U

[5]

[Ga4(C10H9N2)2(PO4)(H0.5PO4)2(HPO4)2(H2PO4)2(H2O)2]•H2O:: a novel one-dimensional chain structure containing four different types of monophosphate [J].

Chen, CY ;

Lo, FR ;

Kao, HM ;

Lii, KH .

CHEMICAL COMMUNICATIONS, 2000, (12) :1061-1062

[6]

SYNTHESIS AND STRUCTURE OF A NOVEL OPEN-FRAMEWORK GALLIUM PHOSPHATE [ME(2)NH(CH2)(2)NHME(2)](2+)[GA4P5O20H](2-).H2O [J].

CHIPPINDALE, AM ;

WALTON, RI ;

TURNER, C .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (12) :1261-1262

[7]

Amine-templated unidimensional phosphate-diphosphates of gallium and vanadium, [NH3CH2CH2NH3][M(H2PO4)(P2O7)] (M = Ga, V) [J].

Chippindale, AM .

CHEMISTRY OF MATERIALS, 2000, 12 (03) :818-822

[8]

New materials in hydrothermal synthesis [J].

Feng, SH ;

Xu, RR .

ACCOUNTS OF CHEMICAL RESEARCH, 2001, 34 (03) :239-247

[9]

THE SYNTHESIS AND CRYSTAL-STRUCTURE OF A NOVEL CLAY-LIKE GALLOPHOSPHATE WITH SUB-UNIT-CELL INTERGROWTHS OF ETHYLENEDIAMINE - [GAPO4(OH)]- 0.5(H3NCH2CH2NH3)2+ [J].

JONES, RH ;

THOMAS, JM ;

HUO, QS ;

XU, RR ;

HURSTHOUSE, MB ;

CHEN, JS .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (21) :1520-1522

[10]

New gallium phosphate frameworks containing 1,4-diaminobutane and 1,5-diaminopentane:: [NH3(CH2)xNH3][Ga4(PO4)4(HPO4)] and [NH3(CH2)xNH3][Ga(PO4)(HPO4)] (x=4 and 5) [J].

Kissick, JL ;

Cowley, AR ;

Chippindale, AM .

JOURNAL OF SOLID STATE CHEMISTRY, 2002, 167 (01) :17-27

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