Cluster build-up in aqueous solution:: synthesis, structure, protonation and catalytic properties of the trinuclear cation [(η6-C6H6)(η6-C6Me6)2Ru3(μ2-H)3(μ3-O)]+

被引：39

作者：

Faure, M ^{[1
]}

Jahncke, M ^{[1
]}

Neels, A ^{[1
]}

Stoeckli-Evans, H ^{[1
]}

Süss-Fink, G ^{[1
]}

机构：

[1] Univ Neuchatel, Inst Chim, CH-2000 Neuchatel, Switzerland

来源：

POLYHEDRON | 1999年 / 18卷 / 20期

关键词：

cluster; trinuclear; ruthenium; arene ligand; oxo cap; aromatic hydrogenation; water-soluble catalyst;

D O I：

10.1016/S0277-5387(99)00170-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The trinuclear ore-capped cluster cation [(eta(6)-C6H6)(eta(6)-C6Me6)(2)Ru-3(mu(2)-H)(3)(mu(3)-O)](+) (2) was synthesised by reacting [(eta(6)- C6Me6)Ru(H2O)(3)](2+) with [(eta(6)-C6Me6)(2)Ru-2(mu(2)-H)(3)](+) in aqueous solution. The single-crystal X-ray structure analysis of the tetrafluoroborate salt shows the cation to contain a H2O molecule hydrogen-bonded to the mu(3)-oxo ligand. Acidification experiments show two protonation steps occuring at this H2O molecule and the oxo cap of the triruthenium cluster. The cluster cation 2 catalyses the hydrogenation of aromatic compounds in aqueous solution under biphasic conditions. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：2679 / 2685

页数：7

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