Polarized fluorescence and orientational order parameters of a liquid-crystalline conjugated polymer

被引:64
作者
Schartel, B
Wachtendorf, V
Grell, M
Bradley, DDC
Hennecke, M
机构
[1] Fed Inst Mat Res & Testing, D-12200 Berlin, Germany
[2] Univ Sheffield, Dept Phys & Astron, Sheffield S3 7RH, S Yorkshire, England
[3] Univ Sheffield, Ctr Mol Mat, Sheffield S3 7RH, S Yorkshire, England
关键词
D O I
10.1103/PhysRevB.60.277
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We report a study of the orientational order of aligned thin films of the liquid crystalline conjugated polymer poly(9,9-dioctylfluorene). Steady state polarized fluorescence measurements were used to determine the ori entational order parameter < P-2> and < P-4> The influence of intermolecular and intramolecular excitation energy transfer on the degree of polarization is discussed. The role of film morphology is also examined by comparison of the results for glassy and crystalline films. [S0163-1829(99)05525-3].
引用
收藏
页码:277 / 283
页数:7
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