Terminal phosphide and dinitrogen molybdenum compounds obtained from pnictide-bridged precursors

被引：49

作者：

Cherry, JPF ^{[1
]}

Stephens, FH ^{[1
]}

Johnson, MJA ^{[1
]}

Diaconescu, PL ^{[1
]}

Cummins, CC ^{[1
]}

机构：

[1] MIT, Cambridge, MA 02139 USA

来源：

INORGANIC CHEMISTRY | 2001年 / 40卷 / 27期

关键词：

D O I：

10.1021/ic015592g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The syntheses of molybdenum terminal phosphide and dinitrogen complexes supported by N-isopropylanilide ligands are not as straightforward as those previously reported for the analogous N-tert-butylanilide complexes, To arrive at these synthetic targets, facile, high-yielding syntheses of bridging pnictide precursors have been developed, and their reduction chemistry has been explored. Cleavage of the reduced mu -E-1 compounds was undertaken using CO and N-2, providing access to the target compounds.

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页码：6860 / +

页数：4

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