Simulation of amphiphilic mesophases using dissipative particle dynamics

被引:107
作者
Jury, S
Bladon, P
Cates, M
Krishna, S
Hagen, M
Ruddock, N
Warren, P
机构
[1] Univ Edinburgh, Dept Phys & Astron, Edinburgh EH9 3JZ, Midlothian, Scotland
[2] Unilever Res, Port Sunlight Lab, Wirral L63 3JT, Merseyside, England
关键词
D O I
10.1039/a809824g
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We study a dense solution of an amphiphilic species using the dissipative particle dynamics (DPD) algorithm, focussing on the smectic mesophase. Since DPD is locally momentum-conserving, it gives at large length scales a faithful representation of the isothermal hydrodynamics of the system. Results are presented for the phase diagram of a minimal amphiphile model, consisting of rigid AB dimers in a solution of C monomers, for the coarsening dynamics of a polydomain smectic phase, and for the formation of a monodomain smectic when shear is applied.
引用
收藏
页码:2051 / 2056
页数:6
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