Functionalized Graphene Sheets as Molecular Templates for Controlled Nucleation and Self-Assembly of Metal Oxide-Graphene Nanocomposites

被引:90
作者
Li, Xiaolin [1 ]
Qi, Wen [2 ]
Mei, Donghai [1 ]
Sushko, Maria L. [1 ]
Aksay, Ilhan [3 ]
Liu, Jun [1 ]
机构
[1] Pacific NW Natl Lab, Richland, WA 99352 USA
[2] Tianjin Univ, Dept Mat Sci & Engn, Tianjin 300072, Peoples R China
[3] Princeton Univ, Dept Chem Engn, Princeton, NJ 08544 USA
关键词
graphene; metal oxide-graphene nanocomposites; molecular templates; self-assembly; LITHIUM-ION BATTERIES; GRAPHITE OXIDE; THIN-FILMS; PERFORMANCE; NANOPARTICLES; COMPOSITES; ELECTRODE; CAPACITY; CATALYST; HYBRID;
D O I
10.1002/adma.201202189
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
By using a combination of theoretical and experimental techniques, it is demonstrated that functionalized graphene sheets (FGS) can function as a new class of molecular templates to direct the nucleation, crystalline phase transition, and self-assembly process of surfactant micelles and metal oxides. Novel, three-dimensional FGS-metal oxide nanocomposite materials with an ordered mesoporous structure can be synthesized. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:5136 / 5141
页数:6
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