Catalysis of the oxidation of triphenylphosphine and of trimethyl phosphite by hydrogen peroxide in the presence of Fe-III compounds

被引：8

作者：

Barton, DHR

Hill, DR

Hu, B

机构：

[1] Department of Chemistry, Texas A and M University, College Station

来源：

TETRAHEDRON LETTERS | 1997年 / 38卷 / 10期

关键词：

D O I：

10.1016/S0040-4039(97)00177-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The oxidation of triphenylphosphine to the corresponding oxide in pyridine is faster in the presence of Fe-III compounds, especially FeCl3. Even greater effects are seen for the oxidation of trimethyl phosphite. (C) 1997 Elsevier Science Ltd.

引用

页码：1711 / 1712

页数：2

共 4 条

[1] The functionalization of saturated hydrocarbons .35. on the intermediates in an Fe-III catalase model in pyridine. Relevance to the catalase enzyme.
Barton, DHR
Hu, B
[J]. TETRAHEDRON, 1996, 52 (31) : 10313 - 10326
[2] THE SELECTIVE FUNCTIONALIZATION OF SATURATED-HYDROCARBONS - GIF CHEMISTRY
BARTON, DHR
DOLLER, D
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[3] THE EFFECT OF TRIPHENYLPHOSPHINE IN THE GOAGGII SYSTEM
BARTON, DHR
BEVIERE, SD
[J]. TETRAHEDRON LETTERS, 1993, 34 (36) : 5689 - 5692
[4] EPR and H-1 NMR spectroscopic characterization of the ferric species formed in the iron picolinate/(pyridine/acetic acid)/HOOH catalytic system for the direct ketonization of methylenic carbons
Sobolev, AP
Babushkin, DE
Shubin, AA
Talsi, EP
[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1996, 112 (02) : 253 - 258

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