Stationary Polaron motion in a polymer chain at high electric fields

被引:42
作者
Basko, DM [1 ]
Conwell, EM [1 ]
机构
[1] Univ Rochester, Dept Chem, Rochester, NY 14627 USA
关键词
D O I
10.1103/PhysRevLett.88.056401
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
We study the stationary motion of a polaron in a conducting polymer in the presence of a high electric field. Using the Su-Schrieffer-Heeger model plus an electric field, we find that at polaron velocities not exceeding the sound velocity, the dissipation of the electronic energy into the lattice occurs via emission of phonons with single selected wave vector. For this case the corresponding contribution to the polaron mobility can be calculated analytically. We discuss the issue of the polaron stability with respect to dissociation in a very high field at supersonic velocities.
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页数:4
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