Synthesis and characterization of p and n dopable interpenetrating polymer networks for organic photovoltaic devices

被引：19

作者：

Lav, T. X. ^{[1
]}

Tran-Van, F. ^{[1
]}

Vidal, F. ^{[1
]}

Peralta, S. ^{[1
]}

Chevrot, C. ^{[1
]}

Teyssie, D. ^{[1
]}

Grazulevicius, J. V. ^{[2
]}

Getautis, V. ^{[2
]}

Derbal, H. ^{[3
]}

Nunzi, J. -M. ^{[3
]}

机构：

[1] Univ Cergy Pontoise, Lab Physicochim Polymeres & Interfaces, EA 2528, 5 Mail Gay Lussac, F-95031 Cergy Pontoise, France

[2] Kaunas Univ Technol, Fac Chem Technol, LT-50254 Kaunas, Lithuania

[3] Univ Angers, CNRS, UMR 6136, PPF Cellules Solaires Photovolta Plast Lab POMA, F-49045 Angers, France

来源：

THIN SOLID FILMS | 2008年 / 516卷 / 20期

关键词：

interpenetrating polymer network; perylene; carbazole; organic solar cells; cross-linking; AFM;

D O I：

10.1016/j.tsf.2007.12.126

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Interpenetrating polymer networks (IPN) based on carbazole derivatives and diacrylate perylene are synthesized in two steps via an in-situ process. From a spin-coated thin film of a mixture of the two precursors, the diacrylate perylene is first photopolymerized to form a network in the presence of the carbazole derivative which is then electropolymerized to elaborate the IPN. Electrochemical characterizations show that the carbazole and perylene are electroactive inside the film which confirm the p and n dopable properties of the IPN. AFM images of the IPNs show a homogenous and smooth surface, compared to single network, which indicate a high quality of association of each network which should allow an efficient p/n bulk heterojunction. (c) 2007 Elsevier B.V All rights reserved.

引用

页码：7223 / 7229

页数：7

共 20 条

[1] ANODIC OXIDATION PATHWAYS OF CARBAZOLES .1. CARBAZOLE AND N-SUBSTITUTED DERIVATIVES [J].